Karen Elson and Jack White
Perhaps one of the hipper, more trendy supermodel-rockstar couples, Karen Elson and Jack White lasted for six years before calling it quits in 2011. Jack White was a founding member of the late 90's band The White Stripes, which he started with ex-wife Meg White. Things definitely got awkward when Karen Elson starred in their music video for "Blue Orchid," where the two fell in love. The couple got married, had two children together, and didn't exactly get their fairy tale ending, as they divorced in 2011 and Elson called for a restraining order from White in 2013.